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US mulls butanol as ethanol substitute in gasoline

01.29.2014  | 

Butanol has a few advantages. It holds 84% of the energy content of gasoline, more than ethanol’s 66%. That means drivers can travel further on a tank with butanol blended in than they would with ethanol.

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By EDUARD GISMATULLIN and KARI LUNDGREN
Bloomberg

Butanol, the gasoline substitute promoted by billionaire Richard Branson, is headed for its debut at US pumps as soon as next year in a challenge to ethanol’s domination of the $26 billion renewable fuels market.

Like ethanol, the colorless alcohol can be brewed from corn, though it packs more energy when mixed into gasoline. Butamax Advanced Biofuel, funded by DuPont and BP, is retrofitting an ethanol plant in Minnesota to begin making butanol in commercial volumes in 2015.

Gevo, backed by French oil producer Total and Branson through his Virgin Green Fund, already runs a distillery 60 miles away. Both say they’ve lined up clients for large-scale deliveries.

“This is the future of renewable fuels,” Branson said. “It’s also hugely versatile so can be created to produce gasoline fuel blends, rubbers, solvents, plastics and jet fuels, which give us scope to enter into a range of markets.”

The nascent industry is trying to take share from ethanol -- both may be blended as a clean fuel with traditional gasoline. Companies like Butamax and Gevo are urging more producers to retrofit their plants on the technological promise that little else is needed -- the distribution networks and vehicle engines work just as well with butanol as they do with ethanol.

The optimism contrasts with a series of disappointments by oil company sponsors. Several have cut or killed various types of biofuels research because they couldn’t get costs down.

Oil Companies

BP, based in London, and Royal Dutch Shell from The Hague have scaled back work on various types of biofuels made with alternatives to corn and sugar cane because of difficulty in making a laboratory success work at a commercial scale.

“There is certainly potential, but there have been quite considerable technical problems in the technology” to ferment butanol, said Clare Wenner, a transport analyst at London-based Renewable Energy Association. “It’s taking a lot longer than anybody thought years ago.”

While butanol has existed for decades as a chemical byproduct of oil refining, making it from crops is a success for the renewables energy industry. The process that now depends on corn as a raw material can be adapted to work with other substances such as sugar cane and cellulosic biomass, resulting in a fuel called biobutanol, according to Butamax.

Biobutanol makers can point to a few successes: BP fueled BMW cars during the London 2012 Olympic Games with the brew. Several gasoline retailers had indicated interest in Butamax’s product, said CEO Paul Beckwith. He didn’t disclose names.

Jet Fuel

“We’ve advanced steadily, and we now are at the phase where we are commercializing the technology,” Beckwith said. “We are spending significant sums of money. The technology is being implemented as we speak.”

Branson is the second-largest investor in Gevo, with an indirect stake of almost 5%, according to data compiled by Bloomberg. The company tested biobutanol with the US Department of Defense and Coast Guard and in racing car fuels. Virgin Atlantic Airways, founded by Branson, is interested in the renewable fuel.

Biobutanol’s promoters say it packs more energy than ethanol and is easier for refiners to blend with gasoline. That would give oil companies more options to comply with rules in the US and European Union mandating more use of biofuels that reduce carbon emissions from petroleum.

‘Significant Change’

“Biobutanol is a drop-in fuel molecule that represents the next significant change required to meet the growth in demand for lower carbon, renewable fuels for transportation,” said Sheila Williams, a spokeswoman at BP. “Commercializing an all- new energy technology properly takes time, despite being one of the most advanced biofuels.”

Butamax has pulled together several ethanol producers, such as Big River Resources and Siouxland Ethanol, willing to switch when the technology is ready. They have about 900 million gallons of combined capacity. The US can make about 14 billion gal/year of ethanol.

Gevo’s plant in Luverne, Minnesota, is running at about two-thirds of 18 million gal/year capacity after a yeast fermenting facility contamination in September 2012, said Brett Lund, the company’s general counsel. Billionaire Vinod Khosla, the co-founder of a venture capital firm bearing his surname, also is an investor in Gevo.

Flexibility Granted

The new fuel would allow policy makers and governments to increase use of renewable energy in gasoline to meet carbon dioxide emission reduction targets.

The US currently limits ethanol to 15% of the content of gasoline for cars made after 2001. Many older cars can only cope with weaker concentrations of the renewable fuel.

The same engines could take a blend that’s 16% butanol, which is less corrosive than ethanol, said Claire Curry, an industry analyst at Bloomberg New Energy Finance in London.

President Barack Obama’s administration in November proposed oil companies for the first time reduce use of ethanol in gasoline. The US’s Environmental Protection Agency plans to approve a new requirement later this year because the industry has almost approached the maximum level of using the renewable diluter for safe use in all nation’s cars.

“With ethanol dominant as a gasoline additive, the US fuel industry simply hasn’t had much reason for adoption of butanol,” said Pavel Molchanov, an analyst with Raymond James Financial. “However, that may be starting to change now that ethanol is hitting a blend wall.”

$6 Billion Investment

Investment in butanol plants may reach $6 billion by 2020 as ethanol makers switch their plants to the new process, according to Bloomberg New Energy Finance.

The brewing process involves fermentation of corn or other biomass sugars by yeast microorganism transforming glucose into biobutanol. The biological yeast is different to the one used for ethanol production. There are some other distillation alterations making refining more efficient.

Gevo’s “products are beginning to enter multiple markets, Branson said. ‘‘Jet fuel is initially the most significant for Virgin but today it is more a question of which opportunities make the most commercial sense.’’

Travel Further

Butanol has a few advantages. It holds 84% of the energy content of gasoline, more than ethanol’s 66%. That means drivers can travel further on a tank with butanol blended in than they would with ethanol.

Biobutanol is also cheaper to blend into gasoline supplies because it has a similar vapor pressure -- the pressure at which a liquid turns into a gas. That means refiners don’t have to strip out butane and other products out of gasoline to stabilize their mixture as they do when they blend in ethanol.



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Sam Joy
05.19.2014

the bottleneck will be extraction and distillation, because the best figures till now stands at 2-3% butanol concentration in the fermentation broth.

Carl Harbert
02.01.2014

Corrosion is a problem. Transportation in special composite lined pipelines could be an answer. Gasoline will be difficult to beat.

Gary Scott
01.31.2014

Branson's worth listening to.
What other sources besides corn can butanol be derived from?

Dilip K Adhikari
01.31.2014

Till butanol is produced from corn it has limitation for supply globally at a reasonable cost and the food vs fuel issues to be addressed.

John Wakefield
01.30.2014

TBA (tertiary butyl alcohol) was used in gasoline in the early 80's as an oxygenate for "clean burning fuel" Then MTBE was mandated, then ethanol and now we have come full circle. The wisdom of our lawmakers is always a source of amusement.

Ilyas Fazil
01.30.2014

No volatility (RVP) issues? There would probably be a volatility limit for Butanol?

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